(2,6-Diisopropylphenyl)(2-thienylmethylene)amine
نویسنده
چکیده
The title compound, C(17)H(21)NS, was prepared by the condensation of thio-phene-2-carbaldehyde with 2,6-diiso-propyl-aniline. It crystallizes with two mol-ecules in the asymmetric unit. The mol-ecules are inter-connected via a C-H⋯N hydrogen bond. The dihedral angles between the thio-phene and phenyl rings are 81.7 (7) and 85.5 (7)°.
منابع مشابه
A monoclinic polymorph of N,N′-bis(2,6-diisopropylphenyl)formamidine
A new polymorph of N,N'-bis-(2,6-diisopropyl-phen-yl)formamidine, C(25)H(36)N(2), is reported, which is different from the previously reported ortho-rhom-bic structure. The mol-ecule crystallizes in the E-anti configuration, with tautomeric disorder of the N-bonded H atoms and no clear distinction between imine and amine functionalities. The mol-ecules form hydrogen-bonded dimers with inter-mol...
متن کامل(2Z,6Z)-N 2,N 2′-Bis(2,6-diisopropylphenyl)-N 1,N 1′-bis(2-methoxyethyl)pyridine-2,6-dicarboxamidine
In the title compound, C(37)H(53)N(5)O(2), the benzene rings make dihedral angles of 84.61 (8) and 67.10 (9)° with the pyridine ring. The crystal structure is stabilized by strong intra-molecular inter-actions. The two (2-methoxyethyl)amine groups are disordered over two positions; the site occupancies are ca 0.6 and 0.4.
متن کاملN-(2,6-Diisopropylphenyl)-N-{3-[(2,6-diisopropylphenyl)imino]butan-2-yl}azanide trichloridostannate(II)
In the title compound, (C(28)H(43)N(2))[SnCl(3)], two pairs of molecular species are present in the asymmetric unit. The employed α-diimine opens up, forming a highly asymmetric ammonium that has its protons at one of the N atoms [N-C= 1.264 (4) and 1.516 (4) Å]. One of the C=N double bonds was oxidized to C-N, which is consistent with the bond length of 1.516 (4) Å. Meanwhile Sn(IV) was reduce...
متن کاملN-(2-Thienylmethylene)naphthalen-1-amine
In the title compound, C(15)H(11)NS, the dihedral angle between the thio-phene and 1-naphthyl rings is 31.42 (11)°. The mol-ecule adopts a trans configuration about the central C=N bond. In the crystal, the mol-ecules are connected via weak C-H⋯π inter-actions.
متن کامل(Acetylacetonato-κ2 O,O′)carbonyl[dicyclohexyl(2,6-diisopropylphenyl)phosphane-κP]rhodium(I)
In the title compound, [Rh(C(5)H(7)O(2)){C(12)H(17)P(C(6)H(11))(2)}(CO)], the Rh(I) atom is coordinated by one carbonyl C, one P and two O atoms, forming a slighlty distorted square-planar configuration.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009